材料科学
丙酮
纳米颗粒
乙醇
化学工程
纳米技术
有机化学
化学
工程类
作者
Wenzhao Zhang,Yajiang Xian,Bingjie Cheng,Ruqu Han,Yamei Zhang,Jun Xiang
标识
DOI:10.1016/j.ceramint.2024.06.222
摘要
This paper presents a novel Fe2TiO5 sensing material for ethanol and acetone detection. Pure Fe2TiO5 nanomaterial was synthesized by a combined solvothermal and calcination method using ferrous sulfate as precursor and urea as a surfactant. The microstructure and surface morphology indicate that Fe2TiO5 belongs to the orthorhombic crystal structure with a Bbmm space group and is composed of loose aggregates of irregular nanoparticles (20–30nm) and abundant pores. X-ray photoelectron spectroscopy analysis indicates that the Fe2TiO5 aggregates contain mixed valence states of Fe2+ and Fe3+ and abundant oxygen vacancies. Examination of gas sensing properties suggests that Fe2TiO5 is an excellent gas-sensitive material. Particularly, at a low optimum operating temperature (240 °C), the gas response of the Fe2TiO5 aggregates to 100 ppm ethanol and acetone is as high as 84.1 and 220.9, respectively. The linear relationship between log(S-1) and logC indicates that Fe2TiO5 can accurately detect ethanol and acetone over a wide concentration range. The gas-sensing performance of the novel Fe2TiO5 nanomaterial can be explained based on the synergistic effect of oxygen vacancy defects and the characteristic surface morphology.
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