Porous carbon derived from ZIF-8 modified molecularly imprinted electrochemical sensor for the detection of tert-butyl hydroquinone (TBHQ) in edible oil

In this manuscript, ZIF-8 derived nanoporous carbon material (ZC) was prepared and used as modification material to construct a molecularly imprinted electrochemical sensor for the direct detection of tert-butyl hydroquinone (TBHQ) in edible oil. Electrochemical characterizations, scanning electron microscopy and X-ray diffraction show that ZC has excellent conductivity, high electrochemical active area and stable porous framework structure. Using TBHQ as template and o-phenylenediamine as functional monomer, the sensor was constructed. Experimental parameters such as the number of polymerization cycle, polymerization speed, and pH of the measured solution, removal and rebinding time were studied. Under optimized conditions, the prepared sensor showed a wider linear range from 1.0 μmol L−1 to 75.0 μmol L−1 with the detection limit of 0.42 μmol L−1 (S/N = 3). Meanwhile, the sensor also expressed good selectivity, repeatability, reproducibility, stability and successfully applied for the determination of TBHQ in real edible oil, giving satisfactory results.