NMR OBSERVATION OF THE SPIN-LATTICE AND SPIN-SPIN RELAXATION IN SOME POLIBUTADIENES WITH DIFFERENT VINYL CONTENTS

Some polybutadienes with different vinyl contents were observed by NMR methods in order to disclose the influence of the microstructure of the polymeric chains on the relaxation of the longitudinal and transverse magnetization. The relaxation process is correlated with the dynamic properties of the polymeric chains. The residual dipolar interaction determined by the rigidity of the polymeric chains is observed by the pseudo-solid echo method and is associated with the vinyl contents of the samples.