材料科学
纳米技术
制作
金属
冶金
医学
病理
替代医学
作者
Víctor Rubio‐Giménez,Marta Galbiati,Javier Castells‐Gil,Neyvis Almora‐Barrios,José Navarro‐Sánchez,Garin Escorcia‐Ariza,Michele Mattera,Thomas Arnold,Jonathan Rawle,Sergio Tatay,Eugenio Coronado,Carlos Martí‐Gastaldo
标识
DOI:10.1002/adma.201704291
摘要
Though generally considered insulating, recent progress on the discovery of conductive porous metal-organic frameworks (MOFs) offers new opportunities for their integration as electroactive components in electronic devices. Compared to classical semiconductors, these metal-organic hybrids combine the crystallinity of inorganic materials with easier chemical functionalization and processability. Still, future development depends on the ability to produce high-quality films with fine control over their orientation, crystallinity, homogeneity, and thickness. Here self-assembled monolayer substrate modification and bottom-up techniques are used to produce preferentially oriented, ultrathin, conductive films of Cu-CAT-1. The approach permits to fabricate and study the electrical response of MOF-based devices incorporating the thinnest MOF film reported thus far (10 nm thick).
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