Highly efficient recovery of heavy rare earth elements by using an amino-functionalized magnetic graphene oxide with acid and base resistance

In the application of various magnetic materials for water treatment, control of surface resistance to acid and alkali corrosion remains largely overlooked, which could greatly extend their service life. We herein prepare amino grafted magnetic graphene oxide composites using a simple one-step cross-link reaction between the graphene oxide and magnetic Fe3O4/C nanoparticles. The as-prepared magnetic graphene oxide composites have long-term stability under acid and alkali solutions and shows an excellent performance in removing Ho(III), a representative rare earth element (REE) from water. The observed adsorption capacity of 72.1 mg Ho(III)/g exceeded that of most magnetic materials previously reported. Regeneration of the magnetic composites was realized in acid and alkali solutions but their structural integrity and physicochemical properties retained even after 18 adsorption-desorption cycles. The current adsorbent also shows excellent adsorption performance for other heavy REEs, such as Er(III), Eu(III), Lu(III), Tm(III), Y(III) and Yb(III). This work can provide a new strategy for constructing an acid and base resistance magnetic graphene oxide for the high-efficient recovery of heavy REEs from aqueous solution.