Enhanced adsorption of perfluorooctanoate (PFOA) onto low oxygen content ordered mesoporous carbon (OMC): Adsorption behaviors and mechanisms

The pollution of perfluorooctanoic acid (PFOA) in water bodies has been a serious threat to environment and human health. Ordered mesoporous carbons (OMCs) with different oxygen contents were prepared and first used for adsorbing PFOA from aqueous solutions. The OMC-900 with a lower oxygen content has a higher PFOA adsorption capacity than the oxygen-rich OMC-700. OMCs require a much shorter time to reach the adsorption equilibrium comparing with other adsorbents reported in literature. The mesopores play an important role in this rapid adsorption kinetics. The pseudo-second-order model better fitted the kinetic data. The multilayers adsorption was proposed for the adsorption of PFOA onto OMCs since the Freundlich isotherm model fits the experimental data well. The micelle or hemi-micelle structures may be formed during the adsorption. Various background salts showed a positive effect on PFOA adsorption due to the salting-out and divalent bridge effects. The humic acid can lead to a discernible reduction in PFOA adsorption by competing for adsorption sites on OMCs. The hydrophobic interaction and electrostatic interaction adsorption mechanisms were proposed and verified by the adsorption data. The high adsorption capacity and fast adsorption kinetics of the OMC make it a potential adsorbent for PFOA removal in engineering applications.