超分子化学
手性(物理)
纳米结构
材料科学
纳米技术
自组装
超分子手性
分子
不对称
有机化学
化学
手征对称破缺
物理
夸克
Nambu–Jona Lasinio模型
量子力学
作者
Li Zhang,Long Qin,Xiufeng Wang,Cao Hai,Minghua Liu
标识
DOI:10.1002/adma.201305422
摘要
Supramolecular chirality, which arises from the nonsymmetric spatial arrangement of components in the self-assembly systems, has gained great attention owing to its relation to the natural biological structures and the possible new functions in advanced materials. During the self-assembling process, both chiral and achiral components are possible to form chiral nanostructures. Therefore, it becomes an important issue how to fabricate these molecular components into chiral nanostructures. Furthermore, once the chiral nanostructure is obtained, will it show new functions that simple component molecule could not? In this research news, we report our recent development in the regulation of chiral nanostructures in soft gels or vesicle materials. We have further developed several new functions pertaining to the soft gel materials, which single chiral molecules could not perform, such as the chiroptical switch, chiral recognition and the asymmetry catalysis.
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