Tetrabutylammonium Decatungstate (Chemo)selective Photocatalyzed, Radical CH Functionalization in Amides

Abstract Photoamidation of electron‐poor olefins has been achieved by means of a radical‐induced CH functionalization in amides. Tetrabutylammonium decatungstate was used as photocatalyst of the reaction and allowed the smooth generation of different carbon‐centered radicals depending on the amide structure.