异质结
光催化
分解水
范德瓦尔斯力
材料科学
析氧
氢
氧化还原
光催化分解水
降级(电信)
纳米技术
化学
化学物理
光电子学
光化学
催化作用
计算机科学
物理化学
电化学
分子
电信
生物化学
有机化学
电极
冶金
作者
Xuefeng Chen,Wenna Han,Zhichao Tian,Qian Yue,Chengxiao Peng,Chao Wang,Bing Wang,Huabing Yin,Qinfen Gu
标识
DOI:10.1021/acs.jpcc.3c00779
摘要
The Z-scheme heterostructure photocatalysts have irreplaceable advantages over other heterostructures due to their ability to separate the spatial carriers and retain strong redox ability. In this study, we explored the SnS2/β-As (β-arsenene) van der Waals heterostructure with Z-scheme properties and suitable band edge positions as a potential photocatalyst for overall water splitting. Under appropriate conditions, the hydrogen evolution reaction (HER) barrier is much closer to 0. Based on the oxidation product criteria, the SnS2/β-As heterostructure photocatalyst may generate multiple end products, including •OH, H2O2, and O2. Moreover, we screen the optimal and most possible reaction pathway OER-III under irradiation among three underlying oxygen evolution reaction (OER) mechanisms, in which the intermediate species HOOH* acts as a bridge for subsequent reactions. The solar-to-hydrogen conversion efficiency of the heterostructure can reach 17.18%. This work provides new insights into designing superior photocatalysts for overall water splitting and recognizing the OER mechanism.
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