Hypervalent Iodide(III)-Mediated Thiofluorination of Alkenes and Alkynes from Thioureas/Thiocarbamoyl Fluorides with Water and Nucleophilic Fluoride Source

This article discloses the unprecedented hypervalent iodide( iii )-mediated thiofluorination of alkenes/alkynes involving the cyclic sulfonium ion intermediate or traditional π-complexes.