Retroreflective Multichrome Microdome Arrays Created by Single‐Step Reflow

Abstract Structural colors are known for their tunability, fade resistance, and eco‐friendliness. Recent advancements have shown that such colors can be efficiently produced using total internal reflection (TIR) on high‐refractive‐index convex microstructures without the need for periodic nanostructures. However, a reproducible, fast, and programmable production strategy for these microstructures is essential for commercial applications. Here, a single‐step method is reported for creating multicolor patterns by transforming photolithographically‐patterned micropillars into microdomes through thermal reflow. These micropillars, uniform in height but varying in diameter, are converted into microdomes that differ in diameter and height, which display a full spectrum of structural colors, creating a versatile color palette. This process enables the production of high‐resolution multicolor graphics using a rainbow color set, with high reproducibility. Additionally, by mixing distinct microdomes and adjusting their densities, a rich variety of color presentations can be achieved, enabling the recreation of arbitrary color images with microdome arrays. The variable heights of the microdomes also allow for dynamic discoloration or color changes through mechanical compression. The high reproducibility and scalability of this method hold significant commercial promise for various optical applications.