荧光粉
光致发光
兴奋剂
材料科学
发光
热稳定性
分析化学(期刊)
化学
光电子学
有机化学
色谱法
作者
Nisar Hussain,Seemin Rubab,Vijay Kumar
标识
DOI:10.1016/j.mseb.2023.116878
摘要
In this study, a series of Eu3+-doped Ba2Tb8(SiO4)6O2 red-emitting phosphors were developed by using a conventional solid-state reaction technique. The crystalline structure, surface morphology, photoluminescence properties, energy transfer processes, and thermal behavior of the Eu3+-doped Ba2Tb8(SiO4)6O2 phosphors were studied. The X-ray diffraction patterns confirmed the formation of the phase, and the Rietveld refinement study revealed that the Eu3+-doped Ba2Tb8(SiO4)6O2 phosphors have a hexagonal crystal structure with the space group P63/m. Energy-dispersive X-ray analysis confirmed the homogenous distribution of Eu3+ ions over the Tb3+ sites. Photoluminescence (PL) spectroscopy was used to test the luminescent properties of the synthesized phosphors. The PL spectra showed that upon UV and blue light exposure, the Eu3+-doped Ba2Tb8(SiO4)6O2 phosphors exhibited red emission associated with the 5D0→7FJ transitions. The mechanisms of concentration quenching and energy transfer were analyzed using Blasse and Dexter's formula. Judd-Ofelt parameters (Ω2, Ω4) and other radiative parameters were analyzed using PL emission spectra to investigate the luminescence behavior of Eu3+-doped Ba2Tb8(SiO4)6O2 phosphors. The results of the thermal stability studies show that Eu3+-doped Ba2Tb8(SiO4)6O2 has good thermal properties with a high activation energy of approximately 0.23 eV. The calculated Commission International del'Eclairage coordinates (x = 0.62 and y = 0.36) of the prepared phosphors confirm that the emitted light is in the red portion with a high color purity of about 99.9%. These findings show that Eu3+-doped Ba2Tb8(SiO4)6O2 phosphors are a viable option for solid-state lighting technology.
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