Intrinsically Stretchable and Healable Polymer Semiconductors

Abstract In recent decades, polymer semiconductors, extensively employed as charge transport layers in devices like organic field‐effect transistors (OFETs), have undergone thorough investigation due to their capacity for large‐area solution processing, making them promising for mass production. Research efforts have been twofold: enhancing the charge mobilities of polymer semiconductors and augmenting their mechanical properties to meet the demands of flexible devices. Significant progress has been made in both realms, propelling the practical application of polymer semiconductors in flexible electronics. However, integrating excellent semiconducting and mechanical properties into a single polymer still remains a significant challenge. This review intends to introduce the design strategies and discuss the properties of high‐charge mobility stretchable conjugated polymers. In addition, another key challenge faced in this cutting‐edge field is maintaining stable semiconducting performance during long‐term mechanical deformations. Therefore, this review also discusses the development of healable polymer semiconductors as a promising avenue to improve the lifetime of stretchable device. In conclusion, challenges and outline future research perspectives in this interdisciplinary field are highlighted.