材料科学
聚丙烯腈
反射损耗
碳纳米纤维
微波食品加热
纳米纤维
碳化
微观结构
静电纺丝
复合材料
纳米技术
光电子学
碳纳米管
聚合物
扫描电子显微镜
复合数
物理
量子力学
作者
Junxiong Xiao,Beibei Zhan,Mukun He,Xiaosi Qi,Xiu Gong,Jingliang Yang,Yunpeng Qu,Junfei Ding,Wei Zhong,Junwei Gu
标识
DOI:10.1002/adfm.202316722
摘要
Abstract Rational manipulation of composition and microstructure design is recognized as an effective pathway to realize multifunctional high‐performance microwave absorber. In this work, necklace‐like hollow polyacrylonitrile (PAN)/carbon nanofibers are designed and constructed through a simple continuous electrospinning‐carbonization‐etching route. Specifically, by varying the carbonization temperature, the ratio of PAN to carbon content of necklace‐like hollow PAN/carbon nanofibers can be effectively regulated, resulting in tunable electromagnetic parameters and conductive loss capacities. After that, the hollow structure is further introduced to improve the feature of lightweight, impedance‐matching characteristics, and interfacial polarization loss ability. Accordingly, the necklace‐like hollow PAN/carbon nanofibers exhibited a frequency bandwidth of 6.60 GHz and a minimum reflection loss of −44.73 dB at 1.76 mm. Both the experimental and theoretical simulation results indicated that the obtained necklace‐like hollow PAN/carbon nanofibers possessed the high chemical stability and excellent microwave absorbing performance, endowing them as the excellent candidates for microwave absorbers in the extreme conditions. Therefore, the findings not only offered a simple pathway to rationally manipulate composition and microstructure but also provided a novel technique to make the most of hollow engineering for strengthening interface polarization loss.
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