Tailoring Advanced CdS Anisotropy‐Driven Charge Spatial Vectorial Separation and Migration via In Situ Dual Co‐Catalyst Synergistic Layout

Tailoring advanced anisotropy-driven efficient separation and migration of photogenerated carriers is a pivotal stride toward enhancing photocatalytic activity. Here, CdS-MoS₂ binary photocatalysts are tailored into a dumbbell shape by leveraging the rod-shaped morphology of CdS and employing an in situ tip-induction strategy. To further enhance the photocatalytic activity, an in situ photo-deposition strategy is incorporated to cultivate MnO_x particles on the dumbbell-shaped CdS-MoS₂. The in situ deposition of MnO_x effectively isolated the oxidatively active sites on the CdS surface, emphasizing the reductively active crystalline face of CdS, specifically the (002) face. Benefiting from its robust activity as a reduction active site, MoS₂ adeptly captures photogenerated electrons, facilitating the reduction of H⁺ to produce hydrogen. The anisotropically driven separation of CdS photogenerated carriers markedly mitigates the Coulomb force or binding force of the photogenerated electrons, thus promoting a smoother migration toward the active site for photocatalytic hydrogen evolution. The hydrogen evolution rate of 35MnO_x-CdS-MoS₂-3 surpasses that of CdS by nearly an order of magnitude, achieving a quantum efficiency of 22.30% at 450 nm. Under simulated solar irradiation, it attains a rate of 42.86 mmol g^-1 h^-1. This work imparts valuable insights for the design of dual co-catalysts, anisotropy-driven spatial vectorial charge separation and migration, and the analysis of migration pathways of photogenerated carriers.