浸出(土壤学)
环境友好型
冰晶石
溶解
电解质
铝
危险废物
材料科学
环境污染
选择性浸出
化学
冶金
无机化学
化学工程
废物管理
环境科学
有机化学
环境保护
土壤水分
电极
土壤科学
物理化学
工程类
生物
生态学
作者
Li Cui,Weihong Wang,Xi Chao,Jian-ming Gao,Fangqin Cheng
标识
DOI:10.1016/j.jclepro.2024.140800
摘要
The electrolytic aluminum industry generates a large amount lithium (Li)-containing electrolytic aluminum slag (EAS) annually, and this can result in severe environmental pollution and wasting of Li resources. This paper proposes a method for recovering Li from the slag using AlCl3 as the leaching agent. The effects of the leaching temperature, AlCl3 concentration, pH, and solid-to-liquid ratio (S/L) on the leaching efficiency of Li+ were systematically examined. The structural transformation during the Li leaching process was revealed by SEM, XRD, 27Al NMR, and XPS analyses. The results indicate that up to 88.3% of Li + can be leached out using 0.85 M of AlCl3 with an S/L of 1:3 at a leaching temperature of 95 °C and pH of 0.5. The addition of AlCl3 played an essential role in the decomposition of cryolite/cryolithionite, ultimately resulting in Al–F fracture and Li+ release in the leaching solution. Moreover, Al3+ enters the interior of the slag to participate in the reconstruction of the chiolite with a low NaF/AlF3 ratio, and reacts with OH− ionized from H2O to form hydroxyl aluminum fluoride species. Fluorine ions were solidified in the leaching residues for subsequent cryolite regeneration. This study not only provides an environmentally friendly process for resource utilization from EAS but also reduces the environmental threat caused by the storage of the hazardous waste.
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