电解质
电池(电)
碳酸丙烯酯
致潮剂
剥离(纤维)
锌
溶剂化
电化学
材料科学
无机化学
化学工程
化学
电镀(地质)
法拉第效率
离子
冶金
电极
有机化学
复合材料
功率(物理)
物理
物理化学
工程类
量子力学
地球物理学
地质学
作者
Zehui Xie,Na Chen,Mingjun Zhang,Mingming Wang,Xinhua Zheng,Shuang Liu,Ruihao Luo,Li Song,Yahan Meng,Zaichun Liu,Zhenyu Li,Wei Chen
出处
期刊:ACS energy letters
[American Chemical Society]
日期:2024-06-14
卷期号:9 (7): 3380-3390
被引量:1
标识
DOI:10.1021/acsenergylett.4c00833
摘要
The chaotropic salt electrolyte (CSE) has become an effective strategy to activate low-temperature aqueous zinc-ion batteries. However, the Zn battery performance has been largely compromised due to the side reaction of active water molecules in CSE. Herein we design a Zn(BF4)2 in a propylene carbonate–water cosolvent electrolyte that facilitates the zinc plating/stripping in a wide temperature range (−40 to 60 °C). Theoretical and experimental results demonstrate the dual effect of propylene carbonate on regulating the hydrogen bond network and reshaping the Zn2+ solvation structure, bringing the antifreezing property and smooth Zn plating/stripping. Consequently, at −20 °C, the Cu//Zn asymmetric cell can achieve stable cycling for over 4000 h at 0.5 mAh cm–2. At −40 °C, the Zn//tetrachlorobenzoquinone full battery can deliver a reversible specific capacity of 77.9 mAh g–1 after 700 cycles. This work presents an effective strategy for the development of high-performance ZIBs in a wide temperature range.
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