Properties and metal binding behaviors of sediment dissolved organic matter (SDOM) in lakes with different trophic states along the Yangtze River Basin: A comparison and summary

有机质 营养水平 环境化学 溶解有机碳 沉积物 富营养化 化学 荧光光谱法 生态学 地质学 荧光 生物 营养物 地貌学 量子力学 物理 有机化学
作者
Tuantuan Fan,Xin Yao,Zhaoli Sun,Dongling Sang,Li Liu,Huanguang Deng,Yinghao Zhang
出处
期刊:Water Research [Elsevier BV]
卷期号:231: 119605-119605 被引量:44
标识
DOI:10.1016/j.watres.2023.119605
摘要

The nature of sediment dissolved organic matter (SDOM) can reflect the environmental background, nutritional status and human activities and is an important part of lakes. The differences in the binding capacity of heavy metals and organic matter in lake sediments with different trophic states at the catchment scale and the mechanism of the differences in binding are still unclear. To solve this problem, we collected bulk SDOMs (< 0.7 μm) from 6 respective lakes (from upstream to downstream) in the Yangtze River Basin (YRB) to qualitatively and quantitatively characterize their properties and metal binding behaviors using excitation-emission matrix spectroscopy combined with parallel factor analysis (EEM-FARAFAC) and two-dimensional correlation spectroscopy of synchronous fluorescence spectroscopy and Fourier transform infrared spectroscopy (2D-SF-COS and 2D-FTIR-COS). The results showed that sediment dissolved organic carbon (SDOC) was mainly enriched in low molecular weight (LMW: < 1 kDa) fractions. The total fluorescence intensity (Fmax) of SDOM from upstream was larger than that from downstream (p = 0.033), and humic-like fluorophores were dominant in these lakes. The Fmax of sediment humic-like components (C1+C2) was closely related to the trophic levels of the lakes. Protein-like substances and oxygen-containing functional groups (C-OH, C=O, and C-O) were preferred in the reaction between SDOM and copper (Cu2+) or cadmium (Cd2+), while a unique binding path was exhibited in the moderately eutrophic DCL. In terms of fluorophore types, higher Cu2+-binding abilities (LogKCu) were observed in the humic-like matter for the lakes in the upper reaches and tryptophan-like matter for the lakes from the midstream and downstream areas of the YRB. Although Cd2+ complexed only with humic-like matter, LogKCd was higher than LogKCu. In terms of molecular weight (MW), the LogKCu/Cd of components were enhanced after MW fractionation. The HMW (0.7 μm - 1 kDa) components possessed higher LogKCu in most lakes (except for CHL and C4). The different fluorophores and molecular weight fractions in SDOM make an important contribution to reducing the ecological risks of heavy metals in lakes.
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