Understanding Anode Capacity Fade in Symmetric Cells

阳极 法拉第效率 材料科学 电极 容量损失 电解质 石墨 淡出 合金 降级(电信) 化学工程 分析化学(期刊) 复合材料 化学 电信 计算机科学 有机化学 物理化学 工程类 操作系统
作者
Yan Zhou,Yijia Liu,T. D. Hatchard,Ben Scott,Yunxia Cao,Simeng Cao,M. N. Obrovac
标识
DOI:10.1149/ma2020-024826mtgabs
摘要

Symmetric cells have been developed to evaluate electrode degradation directly associated with solid electrolyte interphase (SEI) growth. This limits their applications to some certain anodes, such as graphite and Li 4 Ti 5 O 12 . 1 In this work, symmetric cells have been applied to understand the degradation of high energy density anodes, such as Si-alloys, which undergoes multiple degradation mechanisms, including mechanical failure, SEI growth, and excess capacity. The excess capacity is related to the reversible capacity changes, caused by the electrode upper endpoint potential shift. A Li inventory model is developed to interpret anode capacity fade in symmetric cells. The Li inventory model attempts to establish a mathematical relationship between multiple anode degradation processes and measured experimental data, such as cycling charge/discharge capacity. This model allows for the measurement of coulombic efficiencies of individual components of blended electrodes (e.g. alloy + graphite). Figure 1 illustrates the main reactions and side reactions during symmetric cell discharge at i th cycle. Except the main reactions in working electrodes about lithiation and delithiation, the side reactions, as mentioned above, have been included. In this work, a Si-alloy, Si 80 W 20 , 2 was used as an example. One major benefit of symmetric cells is to measure the coulombic efficiency (CE) of electrodes with standard chargers. 3 After deconvolution, the total irreversible capacity (IC) per cycle due to surface reactions on Si 80 W 20 can be obtained from graphite and Si-alloy/graphite blended electrodes. The temperature effects on IC can also be obtained, as summarized in Figure 2 . Reference J. C. Burns et al., J. Electrochem. Soc. , 158 , A1417–A1422 (2011). Y. Liu, B. Scott, and M. N. Obrovac, J. Electrochem. Soc. , 166 , A1170–A1175 (2019) 10.1149/2.0851906jes. Z. Yan and M. N. Obrovac, J. Electrochem. Soc. , 164 , A2977–A2986 (2017). Figure 1 (a) An example of potential curves of electrode A, electrode B, and the symmetric cell during symmetric cell discharge. Illustrations of main and side reactions occurred at electrode A and electrode B during symmetric cell discharge at i th cycle are illustrated in (b) and (c), respectively. The capacity for each reaction during a single symmetric cell discharge/charge process are labelled in the following brackets. Li-Eld , Eld , and Elyt stand for lithiated electrode, delithiated electrode, and electrolyte, respectively. Figure 2 A summary of the average IC of graphite (MAG-E, 20 μm average size, Hitachi) and on Si 80 W 20 per cycle normalized with respect to reversible capacity at different temperatures, as derived from symmetric cells with graphite and alloy/graphite blended electrodes. Figure 1

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
PDF的下载单位、IP信息已删除 (2025-6-4)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
xin_you完成签到,获得积分10
1秒前
毛豆爸爸完成签到,获得积分0
3秒前
4秒前
YamDaamCaa应助科研通管家采纳,获得30
8秒前
欢呼的飞荷完成签到 ,获得积分10
9秒前
13秒前
康复小白完成签到 ,获得积分10
15秒前
nano完成签到 ,获得积分10
16秒前
耍酷的剑身完成签到,获得积分10
21秒前
23秒前
26秒前
热心的棒棒糖完成签到,获得积分10
26秒前
29秒前
29秒前
Cliu1981发布了新的文献求助10
33秒前
沐紫心完成签到 ,获得积分10
34秒前
LJJ完成签到 ,获得积分10
37秒前
桢桢树完成签到 ,获得积分10
37秒前
gdgd完成签到,获得积分10
40秒前
40秒前
lshchoo发布了新的文献求助10
46秒前
47秒前
YamDaamCaa完成签到,获得积分10
47秒前
贾方硕完成签到,获得积分10
49秒前
153266916完成签到 ,获得积分10
51秒前
冰阔落完成签到 ,获得积分10
53秒前
七七完成签到 ,获得积分10
55秒前
小花小宝和阿飞完成签到 ,获得积分10
56秒前
端庄代荷完成签到 ,获得积分10
58秒前
lshchoo完成签到,获得积分10
59秒前
传奇3应助漂亮的忆文采纳,获得10
1分钟前
ivy完成签到 ,获得积分10
1分钟前
1分钟前
ken131完成签到 ,获得积分10
1分钟前
狂风阿来完成签到 ,获得积分10
1分钟前
花生王子完成签到 ,获得积分10
1分钟前
D-L@rabbit完成签到 ,获得积分10
1分钟前
GankhuyagJavzan完成签到,获得积分10
1分钟前
1分钟前
稚祎完成签到 ,获得积分10
1分钟前
高分求助中
A new approach to the extrapolation of accelerated life test data 1000
Cognitive Neuroscience: The Biology of the Mind 1000
Technical Brochure TB 814: LPIT applications in HV gas insulated switchgear 1000
Immigrant Incorporation in East Asian Democracies 600
Nucleophilic substitution in azasydnone-modified dinitroanisoles 500
不知道标题是什么 500
A Preliminary Study on Correlation Between Independent Components of Facial Thermal Images and Subjective Assessment of Chronic Stress 500
热门求助领域 (近24小时)
化学 材料科学 医学 生物 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 遗传学 基因 物理化学 催化作用 冶金 细胞生物学 免疫学
热门帖子
关注 科研通微信公众号,转发送积分 3968559
求助须知:如何正确求助?哪些是违规求助? 3513358
关于积分的说明 11167370
捐赠科研通 3248804
什么是DOI,文献DOI怎么找? 1794465
邀请新用户注册赠送积分活动 875116
科研通“疑难数据库(出版商)”最低求助积分说明 804664