Oxidative degradation of commingled trichloroethylene and 1,4-dioxane by hydroxyl radicals produced upon oxygenation of a reduced clay mineral.

Improper disposal of chlorinated solvents such as trichloroethylene (TCE) and its stabilizer 1,4-dioxane has resulted in extensive contamination in soils and groundwater. Oxidative degradation of these contaminants by strong oxidants has been proposed recently as a remediation strategy, but specific mechanisms and degradation efficiencies are still poorly understood, especially in commingled systems. In this study, a reduced iron-bearing clay (RIC), nontronite (rNAu-2), was oxygenated to produce hydroxyl radicals (•OH) for degradation of TCE and 1,4-dioxane under circumneutral and dark conditions. Results showed that TCE and 1,4-dioxane could be effectively degraded during oxygenation of rNAu-2 in both single and commingled systems. Compared with the single compound system, the degradation rates and efficiencies of TCE and 1,4-dioxane decreased in the commingled system. The negative effect was more significant for TCE than 1,4-dioxane. The commingled TCE and 1,4-dioxane impacted the degradation pattern of each other, due to their difference in •OH scavenging efficiency, surface affinity to rNAu-2 and solubility. Moreover, solution pH, buffer type, rNAu-2 dosage, and dissolved organic matter all affected •OH production and contaminant degradation efficiency. Our findings provide new insights for investigating the natural attenuation of commingled chlorinated solvents and 1,4-dioxane by RIC in redox-fluctuating environments and offer guidance for developing possible in-situ remediation strategies.