硫化
过氧化物
天然橡胶
材料科学
过氧化氢
结晶
分解
过氧化苯甲酰
高分子
高分子化学
热分解
硅橡胶
固化(化学)
有机过氧化物
弹性体
化学
复合材料
化学工程
有机化学
聚合物
共聚物
生物化学
作者
Ján Kruželák,Richard E. Sykora,Ivan Hudeč
出处
期刊:Journal of Polymer Engineering
[De Gruyter]
日期:2014-06-04
卷期号:34 (7): 617-624
被引量:38
标识
DOI:10.1515/polyeng-2014-0034
摘要
Abstract Four different peroxides as curing agents were used to prepare vulcanizates based on natural rubber (NR). The effects of temperature and peroxide concentration on the vulcanization characteristics of rubber compounds, cross-link density ( ν ) and physical-mechanical properties of equivalent vulcanizates were investigated. The results revealed that the vulcanization temperature and also the relative amount of peroxide decomposition products are of significant importance in the properties of vulcanizates. Lower vulcanization temperature and lower concentration of peroxides were found to be better factors, showing a proper balance between the degree of cross-linking of the rubber and degradation of the macromolecular chains by side reactions in relation to the crystallization of NR, which imparts vulcanizates based on NR outstanding properties.
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