纳米纤维素
纤维素
共晶体系
制作
原材料
化学工程
结晶度
深共晶溶剂
化学
材料科学
溶剂
有机化学
复合材料
替代医学
病理
工程类
合金
医学
作者
Yongzhuang Liu,Bingtuo Guo,Qinqin Xia,Juan Meng,Wenshuai Chen,Shouxin Liu,Qingwen Wang,Peng Li,Jian Li,Haipeng Yu
出处
期刊:ACS Sustainable Chemistry & Engineering
[American Chemical Society]
日期:2017-07-20
卷期号:5 (9): 7623-7631
被引量:187
标识
DOI:10.1021/acssuschemeng.7b00954
摘要
The content of cellulose in biomass is important for producing nanocellulose in high yields. Cotton fibers containing ultrahigh purity (∼95%) cellulose are ideal feedstock for nanocellulose production. However, the presence of strong hydrogen bonding between the cellulose chains limits the use of cotton fibers for the production of nanocellulose in a facile and mild process. Here, efficient cleavage of the strong hydrogen bonds in cotton and ultrafast fabrication of cellulose nanocrystals (CNCs) with a high yield of 74.2% were first realized through a 3 min microwave-assisted deep eutectic solvent pretreatment and a subsequent high-intensity ultrasonication process. The obtained CNCs had diameters of 3–25 nm, and lengths ranged between 100 and 350 nm. The CNCs also displayed a relative crystallinity of 82%, and the thermal degradation temperature started from 320 °C. The study provides a green and efficient method for the mass production of cotton CNCs, and is expected to contribute to improving the refinery utilization of cotton feedstock.
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