Fabrication‐controlled morphology of poly(butylene succinate) nano‐microcellular foams by supercritical CO2

材料科学 结晶度 流变学 差示扫描量热法 结晶 扫描电子显微镜 超临界流体 化学工程 微晶 无定形固体 复合材料 纳米- 纳米纤维 化学 结晶学 有机化学 工程类 冶金 物理 热力学
作者
Shuidong Zhang,Yue Xu,Peng Wang,Xiangfang Peng,Jian‐Bing Zeng
出处
期刊:Polymers for Advanced Technologies [Wiley]
卷期号:29 (7): 1953-1965 被引量:11
标识
DOI:10.1002/pat.4304
摘要

Poly(butylene succinate) urethane ionomer (PBSUIs) foams with nano‐microcellular morphology were fabricated using supercritical CO 2 (sc‐CO 2 ) at different parameters. Effect of urethane ionic group (UIG) content (ranged from 1% to 5%) on the rheology and crystallization of PBSUIs were evaluated by intrinsic, dynamic rheological, X‐ray diffraction, and differential scanning calorimetry measurements. The results show that the complex viscosity of PBSUIs vastly improved, while their intrinsic viscosity and crystallinity decreased. They also evidenced that CO 2 promoted the formation of crystallites in the amorphous and increased the X c of PBSU and PBSUIs foams. Scanning electron microscope was employed to explore the influences of UIG content and foaming parameters on the morphologies of PBSUIs microcellular foams, and it revealed that UIG content was the dominated factor. The cell size and cell densities of PBSUIs microcellular foams were smaller than 5.0 micrometers and higher than 1.5 × 10 10 cells/cm 3 , respectively, even foamed at diverse variations of foam temperature and pressure. Interestingly, PBSUIs with 3% and 5% UIG content achieved microcellular foams in nano‐cells, high‐stretched elliptical shape. The mechanism was ascribed that these PBSUIs with high melt viscosities could retard the CO 2 bubbles to merge during the foam process and induce the cells to stretch and orient in depressururization direction. This study proposed a novel method for fabricating PBS nano‐microcellular foams.

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