A Simple and Versatile Approach for the Low‐Temperature Synthesis of Transition Metal Phosphide Nanoparticles from Metal Chloride Complexes and P(SiMe3)3 (Adv. Mater. 49/2023)

Advanced MaterialsVolume 35, Issue 49 2370350 Cover PictureFree Access A Simple and Versatile Approach for the Low-Temperature Synthesis of Transition Metal Phosphide Nanoparticles from Metal Chloride Complexes and P(SiMe3)3 (Adv. Mater. 49/2023) Alexandre Sodreau, Alexandre Sodreau Department of Molecular Catalysis, Max Planck Institute for Chemical Energy Conversion, 45470 Mülheim an der Ruhr, GermanySearch for more papers by this authorHooman Ghazi Zahedi, Hooman Ghazi Zahedi Department of Molecular Catalysis, Max Planck Institute for Chemical Energy Conversion, 45470 Mülheim an der Ruhr, Germany Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Worringerweg 2, 52074 Aachen, GermanySearch for more papers by this authorRıza Dervişoğlu, Rıza Dervişoğlu Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Worringerweg 2, 52074 Aachen, GermanySearch for more papers by this authorLiqun Kang, Liqun Kang Department of Molecular Catalysis, Max Planck Institute for Chemical Energy Conversion, 45470 Mülheim an der Ruhr, GermanySearch for more papers by this authorJulia Menten, Julia Menten Department of Molecular Catalysis, Max Planck Institute for Chemical Energy Conversion, 45470 Mülheim an der Ruhr, GermanySearch for more papers by this authorJohannes Zenner, Johannes Zenner Department of Molecular Catalysis, Max Planck Institute for Chemical Energy Conversion, 45470 Mülheim an der Ruhr, Germany Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Worringerweg 2, 52074 Aachen, GermanySearch for more papers by this authorNicole Terefenko, Nicole Terefenko Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Worringerweg 2, 52074 Aachen, GermanySearch for more papers by this authorSerena DeBeer, Serena DeBeer Department of Molecular Catalysis, Max Planck Institute for Chemical Energy Conversion, 45470 Mülheim an der Ruhr, GermanySearch for more papers by this authorThomas Wiegand, Thomas Wiegand Department of Molecular Catalysis, Max Planck Institute for Chemical Energy Conversion, 45470 Mülheim an der Ruhr, Germany Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Worringerweg 2, 52074 Aachen, GermanySearch for more papers by this authorAlexis Bordet, Alexis Bordet Department of Molecular Catalysis, Max Planck Institute for Chemical Energy Conversion, 45470 Mülheim an der Ruhr, GermanySearch for more papers by this authorWalter Leitner, Walter Leitner Department of Molecular Catalysis, Max Planck Institute for Chemical Energy Conversion, 45470 Mülheim an der Ruhr, Germany Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Worringerweg 2, 52074 Aachen, GermanySearch for more papers by this author Alexandre Sodreau, Alexandre Sodreau Department of Molecular Catalysis, Max Planck Institute for Chemical Energy Conversion, 45470 Mülheim an der Ruhr, GermanySearch for more papers by this authorHooman Ghazi Zahedi, Hooman Ghazi Zahedi Department of Molecular Catalysis, Max Planck Institute for Chemical Energy Conversion, 45470 Mülheim an der Ruhr, Germany Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Worringerweg 2, 52074 Aachen, GermanySearch for more papers by this authorRıza Dervişoğlu, Rıza Dervişoğlu Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Worringerweg 2, 52074 Aachen, GermanySearch for more papers by this authorLiqun Kang, Liqun Kang Department of Molecular Catalysis, Max Planck Institute for Chemical Energy Conversion, 45470 Mülheim an der Ruhr, GermanySearch for more papers by this authorJulia Menten, Julia Menten Department of Molecular Catalysis, Max Planck Institute for Chemical Energy Conversion, 45470 Mülheim an der Ruhr, GermanySearch for more papers by this authorJohannes Zenner, Johannes Zenner Department of Molecular Catalysis, Max Planck Institute for Chemical Energy Conversion, 45470 Mülheim an der Ruhr, Germany Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Worringerweg 2, 52074 Aachen, GermanySearch for more papers by this authorNicole Terefenko, Nicole Terefenko Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Worringerweg 2, 52074 Aachen, GermanySearch for more papers by this authorSerena DeBeer, Serena DeBeer Department of Molecular Catalysis, Max Planck Institute for Chemical Energy Conversion, 45470 Mülheim an der Ruhr, GermanySearch for more papers by this authorThomas Wiegand, Thomas Wiegand Department of Molecular Catalysis, Max Planck Institute for Chemical Energy Conversion, 45470 Mülheim an der Ruhr, Germany Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Worringerweg 2, 52074 Aachen, GermanySearch for more papers by this authorAlexis Bordet, Alexis Bordet Department of Molecular Catalysis, Max Planck Institute for Chemical Energy Conversion, 45470 Mülheim an der Ruhr, GermanySearch for more papers by this authorWalter Leitner, Walter Leitner Department of Molecular Catalysis, Max Planck Institute for Chemical Energy Conversion, 45470 Mülheim an der Ruhr, Germany Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Worringerweg 2, 52074 Aachen, GermanySearch for more papers by this author First published: 07 December 2023 https://doi.org/10.1002/adma.202370350AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Metal Phosphide Nanoparticles In article number 2306621, Alexis Bordet, Walter Leitner, and co-workers report the preparation of metal phosphide nanoparticles through the reaction of metal chloride complexes with tris(trimethylsilyl)phosphine. In the reaction, the release of the by-product SiClMe3 acts as a driving force. The exploitation of the strength of the Si–Cl bond as compared to many metal–Cl bonds is expected to provide easy access to a wide range of transition metal phosphide nanoparticles. Volume35, Issue49December 7, 20232370350 RelatedInformation