加氢脱氧
木质素
生物炭
催化作用
化学
有机化学
制浆造纸工业
牛皮纸
热解
选择性
工程类
作者
Changzhou Chen,Wei Chen,Mengqing Zhou,Yongzhi Xiong,Xialin Ji,Minghao Zhou,Liangliang Zhang,Xiaoping Rao,Jianchun Jiang
标识
DOI:10.1016/j.cej.2024.152353
摘要
Large amount of lignin was produced annually as a byproduct in papermaking and pulping processes, the challenges in disposal methods had posed serious obstacles for advanced carbon materials and value-added chemicals. This study involved the preparation of kraft lignin (KL) loaded metal–organic framework (ZIF-67) material derived Co nanoparticles carbon using various methods to produce kraft lignin biochar-based carbon materials (Co@NPC-KLB). The novel and advanced carbon materials was utilized for lignin derived bio-oil hydrodeoxygenation to generate high value fuels and chemicals. It could achieve nearly 100 % vanillin (VAN) conversion and 88.49 % 2-methoxy-4-methylphenol (MMP) without the extra hydrogen at 240 °C in ethanol. The results demonstrated that highly active and stable Co nanoparticles, large specific surface area, smaller nano Co nanoparticles, strong metal-support interaction and rich Lewis acid sites on the surface of biochar support exhibited a positive promoting effect on VAN hydrodeoxygenation to generate MMP. Furthermore, density functional theory (DFT) also confirmed that synergistic effect of Co nanoparticles and kraft lignin biochar promoted a high adsorption energy of VAN on the surface of kraft lignin biochar, enhanced the catalytic ability of the hydrodeoxygenation process. This study provided a novel approach for utilizing kraft lignin in preparation functional catalysts, opening up new opportunities for designing efficient biochar-based materials for advanced carbon materials and high-value chemicals.
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