Copper-based photocatalysts with natural organic ligands for efficient removal of tetracycline under visible light

The excessive use of broad-spectrum antibiotics, such as tetracycline, presents a significant challenge to human survival and development. Oxygen vacancies (OVs) metal-organic framework (MOF) materials were synthesized using natural organic acids (L-malic acid, L-aspartic acid, and L-asparagine) with similar structures but different charge densities, along with copper as the metal linking agent. The presence of oxygen vacancies in the catalyst provides abundant active sites for photocatalytic reactions. The employment of flexible straight-chain organic ligands devoid of rigid polycyclic rings, combined with the incorporation of different substituents to induce variations in charge density, the resulting catalysts exhibit distinct photocatalytic activities under visible light. Density functional theory calculations confirm that L-asparagine exhibits the largest electron density difference, and the Cu-based MOF (Cu-ASU) synthesized as an organic ligand exhibits the highest photocatalytic activity under visible light excitation. The catalyst displayed remarkable photocatalytic activity against tetracycline antibiotics under identical conditions (with removal rates of 93.5 % for tetracycline, 81.4 % for terramycin, and 95.6 % for chloramphenicol hydrochloride). This provides a novel approach for the design and synthesis of photocatalysts for the removal of antibiotics from water.