电解质
过电位
材料科学
法拉第效率
阴极
电化学
镁
阳极
无机化学
化学工程
杂质
电极
冶金
化学
有机化学
工程类
物理化学
作者
Xueting Huang,Juan Wen,Jinglei Lei,Guangsheng Huang,Fusheng Pan,Lingjie Li
标识
DOI:10.1021/acsami.1c19971
摘要
A cost-effective and highly efficient electrolyte with a wide electrochemical window, high reversibility of Mg plating/stripping, non-/low-corrosivity, good compatibility with cathode materials, and tolerance of trace water and impurity is crucial for the commercialization of rechargeable magnesium batteries. In this work, a novel boron-centered non-nucleophilic electrolyte that meets all the above requirements is prepared via a facile and economic approach from the raw materials B(TFE)3/MgCl2/CrCl3/Mg (BMCM). The as-prepared BMCM electrolyte is mainly composed of tetracoordinated anions [B(TFE)4]- and solvated cations [Mg2(μ-Cl)2(DME)4]2+. The BMCM electrolyte demonstrates attractive electrochemical performance, with a low overpotential (∼139 mV), a high Coulombic efficiency (∼97%), a high anodic stability (∼3.5 V vs Mg/Mg2+), and a long-term (more than 500 h) cycling stability. Moreover, BMCM shows good compatibility with the CuS cathode material. The CuS|BMCM|Mg full cell delivers a discharge specific capacity of 231 mAh g-1 (at 56 mA g-1), which can retain ∼88% even after 100 cycles. Importantly, the BMCM electrolyte is cost-effective and tolerant of trace impurity and water, which has great potential to be commercialized. This work is expected to promote the development of practical rechargeable magnesium batteries.
科研通智能强力驱动
Strongly Powered by AbleSci AI