沸石
松香
催化作用
甘油酯
产量(工程)
原位
路易斯酸
化学
有机化学
路易斯酸催化
材料科学
树脂酸
复合材料
脂肪酸
作者
Xiaoxiao Wang,Fang Guo,Yue Yu,Zhenmin Liu,Ying‐Chun Wang,Hongyan Sun,Xianjun Liu,Yongbing Xue,Xianxian Wei,Shaoqing Guo
出处
期刊:ACS omega
[American Chemical Society]
日期:2020-12-07
卷期号:5 (49): 31543-31550
被引量:9
标识
DOI:10.1021/acsomega.0c03427
摘要
LaZSM-5 zeolite was synthesized by the in situ method and used as catalysts to catalyze the synthesis of rosin glyceride. As a comparison, ZSM-5 was also synthesized and used as catalysts to catalyze the synthesis of rosin glyceride. The synthesized ZSM-5 and LaZSM-5 zeolite catalysts were characterized and analyzed. The experimental results showed that the in situ synthesis of LaZSM-5 made La into the skeleton of ZSM-5 zeolite and increased the amount of Lewis acid on the LaZSM-5 zeolite. Also, Lewis acid was the key to liquid-phase esterification reaction. Compared with ZSM-5 zeolite, LaZSM-5 zeolite contributed to a higher yield and better stability as a catalyst for the synthesis of rosin glycerides.
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