Thermostable Organo‐phosphor: Low‐Vibrational Coordination Polymers That Exhibit Different Intermolecular Interactions

Novel thermostable organo-phosphor compounds composed of coordination polymers are reported. Tight-binding structures with intermolecular interactions of the coordination polymer induce both thermostability (decomposition point >300 °C) and high emission quantum yield (ΦLn=83 %). Their structures (see picture), thermogravimetric analyses, and remarkable photophysical properties are presented for the first time.