材料科学
阳极
纳米线
电化学
静电纺丝
锂(药物)
纳米技术
电导率
离子
氧化铌
铌
热扩散率
化学工程
锂离子电池
电池(电)
复合材料
电极
冶金
有机化学
物理化学
聚合物
功率(物理)
内分泌学
化学
工程类
物理
医学
量子力学
作者
Cheng Jiang,Tingting Liu,Nengbing Long,Xing Cheng,Na Peng,Jundong Zhang,Runtian Zheng,Haoxiang Yu,Jie Shu
标识
DOI:10.1016/j.ceramint.2019.05.217
摘要
Niobium-based compounds are extensively studied as anode materials for LIBs on account of the great structural stability and high theoretical capacity. Among them, VNb9O25 has an attractive theoretical capacity (416 mAh g−1). Unfortunately, low electronic conductivity and Li+ diffusivity hinder its practical application. To overcome above barriers, VNb9O25 nanowires were synthesized directly by electrospinning method. As expected, VNb9O25 nanowires deliver an outstanding capacity retention (92.1% after 200 cycles) and a robust rate property (90.7 mAh g−1 at 1000 mA g−1). Thus, as-electrospun VNb9O25 nanowires are alternative promising anode materials for LIBs.
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