共沉淀
电化学
阴极
堆积
晶体结构
钴
镍
结晶学
Crystal(编程语言)
材料科学
单晶
无机化学
化学
电极
冶金
物理化学
有机化学
计算机科学
程序设计语言
作者
Hailan Feng,Yuxing Xu,Yuncheng Zhou,Jiechen Song,Qiangqiang Tan
出处
期刊:ACS omega
[American Chemical Society]
日期:2024-02-05
卷期号:9 (6): 6994-7002
标识
DOI:10.1021/acsomega.3c08782
摘要
In this paper, the effect of the structure characteristics of the precursor on the electrochemical properties of a single-crystal cobalt-free high-nickel LiNi0.9Mn0.1O2 cathode is systematically studied. Precursors with different morphologies are synthesized by adjusting the coprecipitation reaction conditions. The results of SEM and XRD show that with the increase in the orderly stacking arrangement of internal primary nanosheets of Ni0.9Mn0.1(OH)2, the exposed active {010} planes at the surface increase. The prepared cathode materials finally inherit the structural features of the precursor, and the single-crystal Co-free Ni-rich LiNi0.9Mn0.1O2 cathode with highly exposed active {010} planes shows a well-ordered crystal structure and low Li+/Ni2+ cation mixing. The characterization results reveal that the high percentage of {010} planes will improve the Li+ transportation kinetics, decrease electrochemical impedance, and significantly alleviate the accumulation of rock-salt phases. Therefore, the material with this structure shows good electrochemical performance.
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