Lanthanide doped Cs2Ag1-xNaxBiCl6 as an efficient anti-counterfeiting and information encryption material

镧系元素 材料科学 发光 光子上转换 兴奋剂 激发 离子 光电子学 化学 有机化学 工程类 电气工程
作者
Hao Zhang,Huiping Gao,Yuefeng Liu,Yunpeng Fan,Yayong Hu,Wenwu You,Gencai Pan,Huafang Zhang,Zhenlong Zhang,Yanli Mao
出处
期刊:Ceramics International [Elsevier BV]
卷期号:50 (3): 5234-5241 被引量:3
标识
DOI:10.1016/j.ceramint.2023.11.270
摘要

Luminescent anti-counterfeiting materials based on double perovskite has attracted people's attention due to its low cost, high stability, easy preparation, and environmental friendliness. However, advanced anti-counterfeiting and information encryption call for materials with multi-color emission and multimode excitation to avoid being imitated and replaced. In this study, upconversion luminescence of lanthanide Cs2Ag1-xNaxBiCl6 were investigated through adjusting the feed ratio of Ag + to Na+ and controlling the types and concentrations of the lanthanide ions. Cs2Ag0.4Na0.6BiCl6-Yb-Er emits green light under excitation at 980 and 1540 nm. Cs2Ag0.4Na0.6BiCl6-Yb-Tm and Cs2Ag0.4Na0.6BiCl6-Yb-Ho show purple and white light under excitation at 980 nm, respectively. Under excitation at 365 nm, the Cs2Ag0.4Na0.6BiCl6-Yb-Er presents yellow light, while both Cs2Ag0.4Na0.6BiCl6-Yb-Tm and Cs2Ag0.4Na0.6BiCl6-Yb-Ho exhibit orange-red light. Additionally, Yb ions doping make three samples present good near-infrared luminescent properties. At last, the high level anti-counterfeiting and information encryption applications based on lanthanide doped Cs2Ag1-xNaxBiCl6 were designed and implemented, using the characteristics of the material's luminescence properties that differ with the type of doping, excitation wavelength, and excitation power. This work indicates that lanthanide doped double perovskite has the potential to obtain more efficient anti-counterfeiting materials and information encryption materials.
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