氯铂酸
硅氢加成
甲苯
催化作用
摩尔比
材料科学
溶剂
高分子化学
质量分数
硅油
化学工程
烯丙基重排
有机化学
化学
复合材料
铂金
工程类
作者
Cai Yun Zhang,Xinghua Zhang
出处
期刊:Advanced Materials Research
日期:2014-08-13
卷期号:1004-1005: 277-281
标识
DOI:10.4028/www.scientific.net/amr.1004-1005.277
摘要
Polyether-modified polysiloxane was synthesized by hydrosilylation, using allylic alcohol polyether and polysiloxane as materials, toluene as solvent and chloroplatinic as catalyst. The effect of technology conditions on conversion rate of hydrogenous silicone oil was discussed and chemical structure of product was characterized. The results show that the optimum technology is: the reaction temperature is 95°C, time is 5h, the molar ratio of polysiloxane to polyether is 1:1.2, the dosage of catalyst is 30ug/g and the mass fraction of the toluene is 25% of the system.
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