Cobaltaelectro‐Catalyzed C−H Activation with Carbon Monoxide or Isocyanides

Abstract Electrochemical oxidative C−H/N−H activations with isocyanides have been realized with a versatile cobalt catalyst. The widely applicable cobalt catalysis manifold further enabled electrooxidative C−H/N−H carbonylations with carbon monoxide under ambient conditions. The C−H functionalizations were efficiently realized with ample scope and outstanding functional group tolerance in a user‐friendly undivided cell setup.