滴定法
化学
二茂铁
电化学
选择性
配体(生物化学)
离子
傅里叶变换红外光谱
元素分析
单晶
质子核磁共振
无机化学
核化学
结晶学
物理化学
立体化学
受体
电极
有机化学
催化作用
物理
生物化学
量子力学
作者
Yi Huang,Jie-Shuang Lin,Wenkai Zhang,Bingguang Zhang,Qiaozhen Sun
标识
DOI:10.1016/j.inoche.2019.04.032
摘要
A new ferrocene based receptor 1,2-bis(ferrocenylmethylthio)-maleonitrile (FcMNT) was synthesized and characterized by elemental analysis, FTIR, NMR and X-ray single crystal diffraction. The ligand showed a high selection for Hg2+ in DMF or DMF/H2O mixed solution. Upon addition of Hg2+ in DMF, the receptor showed an obvious color change and significant UV–vis spectroscopic response. Electrochemical titrations revealed that the receptor sensed Hg2+ in high selectivity with an anodic shift of 307 mV. The 13CNMR titrations confirmed that the Hg2+ interacted with the S atoms of FcMNT when the amount of Hg2+ was under 1.0 equiv.; the Hg2+ interacted with CC and CN groups when the amount of Hg2+ was above 1.0 equiv.
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