库仑法
电解质
法拉第效率
石墨
电极
溶解
材料科学
离子
化学
分析化学(期刊)
无机化学
电化学
冶金
物理化学
色谱法
有机化学
作者
Aaron Smith,James T. Burns,Deijun Xiong,J. R. Dahn
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:2011-08-15
卷期号:158 (10): A1136-A1142
被引量:262
摘要
The High Precision Charger at Dalhousie University can be used to accurately measure the Coulombic Efficiency (CE) and the charge and discharge capacity endpoint slippages per cycle (Δ d and Δ c , respectively) of Li-ion full cells and Li/electrode half cells. If the CE is not exactly 1.0000 and the endpoints slip then this must be due to parasitic reactions between the electrode materials and the electrolyte in the cell. The various parasitic currents and charges associated with: solid electrolyte interface growth; electrolyte oxidation; transition metal dissolution and positive electrode damage are considered using a Li inventory model. The mathematical relations between the parasitic currents and the measured CE, Δ d and Δ c are derived. Example data collected on both Li/graphite, Li/LiCoO 2 half cells as well as both graphite/LiCoO 2 and graphite/LiMn 2 O 4 Li-ion cells are used to illustrate how high precision coulometry results can be used to help elucidate cell degradation mechanisms.
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