Modification of polylactide by poly(ionic liquid)-b-polylactide copolymer and bio-based ionomers: Excellent toughness, transparency and antibacterial property

Polylactide (PLA) is one of the most attractive bioplastics as it can be produced from nontoxic renewable feedstock. However, its inherently poor toughness greatly limits its large-scale application. Cost-effectively toughening PLA without sacrificing its transparency remains a big challenge. We herein prepared an imidazolium-based poly(ionic liquid)-b-PLA copolymer (ILA) and ionomers as toughening agent for PLA through an integrative approach including continuous-monomer-feeding copolymerization, quaternization reaction, ion exchange and inter-ionomers blending. By blending PLA with the ILA and ionomers, we successfully obtained PLA materials with combined features including high toughness, good transparency and antibacterial properties. The effects of regulated ionomer composition and ILA compatibilizer on phase morphology, mechanical properties and transparency of the blends were systematically studied. The optimum formulation (PLA/E12/ILA 60/40/5) shows an impressive transmittance of 89-93 %, high impact strength of 45 kJ/m2 and elongation at break at 170 %, which are about 17 and 24 times that of pure PLA, respectively. More interestingly, the presence of imidazolium cation and anion groups endows the blends with attractive antibacterial properties. Ion exchange between ILA copolymer and the imidazolium-containing ionomeric system leads to a synergistic effect of compatibilization and efficient toughening, providing a new strategy for develop high performance PLA materials.