电容去离子
铜
阴极
废水
材料科学
电容感应
离子
多孔性
化学工程
电化学
电极
冶金
化学
环境工程
环境科学
复合材料
电气工程
工程类
有机化学
物理化学
作者
M. Tang,Xiaoyan Shen,Lin Zhao,Shiyong Wang,Sihao Lv,Aiguo Zhou,Bin Zhu,Gang Wang
标识
DOI:10.1016/j.seppur.2024.128169
摘要
Water pollution is a pressing environmental concern in today's world. Among the various pollutants found in aquatic environments, heavy metals, due to their high activity and wide range, are of particular concern. In the field of aqueous copper ion batteries, CuSe and CuS have been recognized as excellent copper storage materials. Selenium (Se) exhibits remarkable cyclic stability but limited reversible capacity, whereas sulfur (S) shows superior reversible capacity but inadequate cyclic stability. In this study, we synthesized a heterogeneous hollow core–shell structure known as CuS@CuSe. This structure was achieved by utilizing Cu2O as a template for layer-by-layer sulfuration and selenisation processes. The CuS@CuSe structure provides more electrically active sites and lowers the energy barrier for reactions. As a result, when used as cathode materials in capacitive deionization (CDI), CuS@CuSe demonstrates exceptional electroadsorption capacity (647.0 mg g−1), a high ion transport rate of 17.1 mg g−1 min−1, and superior cycling properties. The adsorption mechanism of CuS@CuSe was investigated through characterization techniques and density functional theory (DFT) calculations. These findings not only contribute to the understanding of the adsorption process but also provide valuable insights for the design and development of effective electrode materials capable of selectively capturing copper ions from wastewater.
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