Vapor–Solid Interface Synthesis of Highly Crystalline Covalent Triazine Frameworks for Use as Efficient Photocatalysts

Abstract Harsh synthetic conditions for crystalline covalent triazine frameworks (CTFs) and associated limitations on structural diversities impede not only further development of functional CTFs, but also practical large‐scale synthesis. Herein, a mild and universal vapor–solid interface synthesis strategy is developed for highly crystalline CTFs employing trifluoromethanesulfonic acid vapor as catalysts. A series of highly ordered simple and functional CTFs (CTF‐TJUs) can be facilely produced. In particular, the porphyrin‐involved functional CTF (CTF‐TJU‐Por1) with high crystallinity is synthesized for the first time via this universal approach. The mechanism of vapor‐catalyzed trimerization of nitrile monomers is thoroughly investigated through semi in situ characterizations. As a proof of concept, the photocatalytic performance of synthesized CTFs for water splitting is evaluated. CTF‐TJU‐133 exhibits significantly greater photocatalytic rates for hydrogen (4.35 µmol h −1 ) and oxygen (2.18 µmol h −1 ) evolutions during overall water splitting under visible light irradiations compared to other CTF‐TJUs, representing one of the highest values among reported CTF photocatalysts. Further studies reveal that enhanced photocatalytic performance of CTF‐TJU‐133 results from optimized band structure, extended visible‐light absorption, and high carrier separation efficiency. This study provides a promising strategy to synthesize various simple and functional CTFs, which significantly enriched diversities of CTF family for different application purposes.