Imaging Locally Inhomogeneous Properties of Metal Halide Perovskites

Abstract Metal halide perovskites (MHPs) are a perfect example of state‐of‐the‐art photovoltaic materials whose compositional and structural diversity, coupled with utilization of low‐temperature processing, can undesirably result in spatially inhomogeneous properties that locally vary within the material. This complexity of MHPs requires sensitive imaging characterization methods at the microscopic level to gauge the impact of such inhomogeneities on device performance and to formulate mitigation strategies. This review consolidates properties of MHPs that are susceptible to local variations and highlights appropriate imaging techniques that can be employed to map them. Inhomogeneities in morphology, emission, electrical response, and chemical composition of MHP thin films are specifically considered, and possible microscopic techniques for their visualization are reviewed. For each type of microscopy, a short discussion about spatial resolution, sample requirements, advantages, and limitations is provided, thus leaving the reader with a guide of available imaging characterization tools to evaluate inhomogeneities of their MHPs.