吡啶
化学
结晶学
配位聚合物
双锥
氢键
氧原子
立体化学
晶体结构
分子
药物化学
有机化学
作者
Huifang Wu,Xu‐Dong Chen,Miao Du
标识
DOI:10.1107/s1600536806052354
摘要
In the title complex, [Cd2(C7H3NO4)2(CH3OH)2(H2O)]n, each Cd atom has a pentagonal–bipyramidal geometry (CdNO6). The anionic pyridine-2,6-dicarboxylate (pydc) ligands adopt a κ5O:O,N,O′:O′ coordination mode. Two symmetry-related CdII centers are linked by a pair of carboxylate groups from two pydc ligands as well as a bridging oxygen from a water molecule located on a twofold axis, to form a dinuclear unit. These dinuclear units are further connected via carboxylate O atoms to build a one-dimensional polymeric chain. O—H⋯O hydrogen bonds are observed within this chain.
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