In order to timely discriminate wheat with different mildew rates, a Dyes/Dyes-Cu-MOF paper-based colorimetric sensor array was designed. Using array points to capture volatile gases of wheat with different mildew rates, and output RGB values. The correlation between ΔR/ΔG/ΔB values and odor components was established. The ΔG values of array points 2' and 3' showed the best correlation with mildew rate, with R2 of 0.9816 and 0.9642. The ΔR value of 3 and the ΔG value of 2 correlate well with the mildew rate, with R2 of 0.9625 and 0.9502, respectively. Then, the ΔRGB values are subjected to pattern recognition processing, and LDA achieves 100% correct discrimination for all samples, or divides high and low mildew areas. This method provides an odor-based monitoring tool for fast, visual and nondestructive evaluation of food safety and quality through visualization of odors produced by different mildew rates.