Isotope Effects on State-to-State Photodissociation Dynamics of D2S in Its First Absorption Band

State-to-state photodissociation dynamics of D₂S in its first absorption band were explored by utilizing recently developed diabatic potential energy surfaces (PESs). Quantum dynamics calculations, involving the first two strongly coupled ¹A″ states, were executed employing a Chebyshev real wavepacket method. The nonadiabatic channel via the conical intersection (CI) is facile, direct, and fast, leading to the production of rotationally and vibrationally cold SD(X̃²Π). The calculated absorption spectrum, product state distributions, and angular distributions are in reasonable agreement with the experimental results, although some discrepancies exist at 193.3 nm. Compared with H₂S, there are obvious isotope effects on rotational state distributions for D₂S photodissociation in its first absorption band. Moreover, we scrutinize the variation of product state distributions as a function of photon energy and the vibrational mediated photodissociation of the parent molecule. Due to the diverse shapes of the three fundamental vibrational wave functions, photoexcited wavepackets access distinct segments of the upper-state PES, resulting in a disparate absorption spectrum and ro-vibrational distributions via the nonadiabatic transition. This study provides a comprehensive figure of the isotopic effect and wavelength dependence on the photofragmentation behaviors from D₂S photodissociation, which should attract more experimental and theoretical attention to this prototypical system.