Visible‐Light‐Induced Three‐Component Tetrafluoroethyl‐heteroarylation of Alkenes with 1,1,2,2‐Tetrafluoroethanesulfonyl Chloride and Quinoxalin‐2(1H)‐ones

1,1,2,2-Tetrafluoroethyl-containing compounds are valuable structures due to their unique physicochemical properties, which have increasing potential application in drug discovery. However, synthetic methods for preparing such compounds are rare. Herein, we report the first use of 1,1,2,2-tetrafluoroethanesulfonyl chloride to introduce the HCF2 CF2 group into organic molecules via a three-component, radical tetrafluoroethyl-heteroarylation of alkenes with readily available quinoxalin-2(1H)-ones. This method provides a new and facile approach for late-stage functionalization of potential biologically active molecules.