材料科学
阳极
法拉第效率
电解质
石墨烯
化学工程
氧化物
双层
复合数
锂(药物)
复合材料
纳米技术
电极
膜
化学
冶金
生物化学
医学
工程类
内分泌学
物理化学
作者
Chuanfa Li,Shaohong Liu,Chen‐Guang Shi,Ganghao Liang,Zhitao Lü,Ruowen Fu,Dingcai Wu
标识
DOI:10.1038/s41467-019-09211-z
摘要
Abstract Lithium metal batteries have been considerably limited by the problems of uncontrolled dendritic lithium formation and the highly reactive nature of lithium with electrolytes. Herein, we have developed functional porous bilayer composite separators by simply blade-coating polyacrylamide-grafted graphene oxide molecular brushes onto commercial polypropylene separators. Our functional porous bilayer composite separators integrate the lithiophilic feature of hairy polyacrylamide chains and fast electrolyte diffusion pathways with the excellent mechanical strength of graphene oxide nanosheets and thus enable molecular-level homogeneous and fast lithium ionic flux on the surfaces of electrodes. As a result, dendrite-free uniform lithium deposition with a high Coulombic efficiency (98%) and ultralong-term reversible lithium plating/stripping (over 2600 h) at a high current density (2 mA cm −2 ) are achieved for lithium metal anodes. Remarkably, lithium metal anodes with an unprecedented stability of more than 1900 h cycling at an ultrahigh current density of 20 mA cm −2 are demonstrated.
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