膜
石墨烯
材料科学
碳纳米管
氧化物
化学工程
水溶液中的金属离子
金属
离子
无机化学
碳纤维
纳米管
纳米技术
复合材料
有机化学
化学
复合数
冶金
工程类
生物
遗传学
作者
Marcin Musielak,Anna Gągor,Beata Zawisza,E. Talik,Rafał Sitko
标识
DOI:10.1021/acsami.9b11214
摘要
Graphene oxide (GO) has an excellent adsorption capacity toward metal ions. Therefore, it is widely recognized as an auspicious material for fabrication of membranes applied in metal ion separation. However, GO membranes are not stable in aqueous solution because of electrostatic repulsion between GO nanosheets which are negatively charged. This paper shows that stable GO membranes can be easily obtained by the noncovalent interaction of GO with oxidized carbon nanotubes (CNTs). The experiment also shows that the GO/CNTs membranes can be used for the effective adsorption of metal ions. The kinetic data, adsorption isotherms, competitive adsorption experiment, and X-ray photoelectron spectroscopy indicate that the adsorption of metal ions is based on chemisorption. The membranes are remarkably durable in acidic, neutral, and basic solutions. Although the significant stabilization of the membranes by CNTs is observed, they strongly influence the adsorption process. Our study reveals that even a small amount of CNTs (GO/CNTs in the ratio 8:1) significantly reduces adsorption capacities of the membranes which were as follows: 37, 40, 50, 42, 48, and 98 mg g-1 for Co(II), Ni(II), Cu(II), Zn(II), Cd(II), and Pb(II), respectively. The reduction of the membrane adsorption capacities results from the creation of micro- and nanochannels formed by entangled CNTs. Durability and adsorptive properties of studied membranes indicate their potential use for the removal of metals from water.
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