Effect of Temperature-Induced Aging on the Gas Permeation Behavior of Thin Film Composite Membranes of PIM-1 and Carboxylated PIM-1

Polymers of intrinsic microporosity (PIMs) are a class of promising gas separation materials due to their high membrane permeabilities and reasonable selectivities. When processed into thin film composite (TFC) membranes, their high gas throughput aligns closely with industrial requirements, but they are prone to physical aging and plasticization effects. TFC membranes based on the prototypical PIM-1 and its carboxylated derivative cPIM-1 exhibit temperature-dependent gas permeation behavior, which has not been extensively studied before. In single CO