Visible-light-induced cascade sulfonylation/cyclization of N-propargylindoles with aryldiazonium tetrafluoroborates via the insertion of sulfur dioxide

A simple and efficient visible-light-catalyzed cascade sulfonylation/cyclization of N-propargylindoles with K₂S₂O₅ and aryldiazonium tetrafluoroborates for the construction of 2-sulfonyl-substituted 9H-pyrrolo[1,2-a]indoles is developed.