荧光粉
材料科学
发光
兴奋剂
激发态
近红外光谱
激活剂(遗传学)
紫外线
分析化学(期刊)
发射光谱
红外线的
光电子学
光致发光
可见光谱
持续发光
光学
谱线
化学
原子物理学
物理
生物化学
热释光
色谱法
天文
基因
作者
Ganggang Guo,Tao Yin,Mengrui Dong,J. Nie,Y.J. Zhang,Zhenyang Liu,Fenghe Wang,Li Guan,Lijin Xu
出处
期刊:Optics Express
[The Optical Society]
日期:2023-07-20
卷期号:31 (16): 25978-25978
被引量:1
摘要
Although Cr3+ as activator for Near infrared (NIR) phosphors has been widely studied, the peaks of Cr3+ emission spectra in most hosts are less than 1000 nm. Nd3+ as an activator in many hosts has a wide distribution of absorption peaks in the Ultraviolet-visible-Near infrared (UV-vis-NIR) band, especially in the 650-900 nm band for effective NIR to NIR Stokes luminescence (4F3/2→4I9/2, 4F3/2→4I11/2 transitions). Therefore, Cr3+, Nd3+ co-doping to achieve the emission in the NIR II region (1000-1700nm) is very meaningful. Here, we report La2CaZrO6(LCZO): Cr3+, Nd3+ NIR phosphors with emission spectra covering an ultra-wide range of 700-1400 nm and reveal their luminescence mechanism. The energy transfer efficiency of Cr3+ for Nd3+ can be as high as 88.4% under 471 nm blue light excitation. In the same case, the integrated intensity of the emission spectra of Cr3+, Nd3+ co-doped can reach 847% of that of Nd3+ alone and 204% of that of Cr3+ alone. Finally, the combination of commercial blue light chips and Cr3+, Nd3+ co-doped NIR phosphors shows great potential for applications in face recognition, night lighting, and angiography.
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