Selective Catalytic Monoreduction of Phthalimides and Imidazolidine‐2,4‐diones

Angewandte Chemie International EditionVolume 50, Issue 39 p. 9180-9184 Communication Selective Catalytic Monoreduction of Phthalimides and Imidazolidine-2,4-diones† Shoubhik Das, Shoubhik Das Leibniz-Institut für Katalyse e.V. (LIKAT) an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Germany) http://www.catalysis.deSearch for more papers by this authorDr. Daniele Addis, Dr. Daniele Addis Leibniz-Institut für Katalyse e.V. (LIKAT) an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Germany) http://www.catalysis.deSearch for more papers by this authorLeif R. Knöpke, Leif R. Knöpke Leibniz-Institut für Katalyse e.V. (LIKAT) an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Germany) http://www.catalysis.deSearch for more papers by this authorDr. Ursula Bentrup, Dr. Ursula Bentrup Leibniz-Institut für Katalyse e.V. (LIKAT) an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Germany) http://www.catalysis.deSearch for more papers by this authorDr. Kathrin Junge, Dr. Kathrin Junge Leibniz-Institut für Katalyse e.V. (LIKAT) an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Germany) http://www.catalysis.deSearch for more papers by this authorProf. Dr. Angelika Brückner, Prof. Dr. Angelika Brückner Leibniz-Institut für Katalyse e.V. (LIKAT) an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Germany) http://www.catalysis.deSearch for more papers by this authorProf. Dr. Matthias Beller, Corresponding Author Prof. Dr. Matthias Beller [email protected] Leibniz-Institut für Katalyse e.V. (LIKAT) an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Germany) http://www.catalysis.deLeibniz-Institut für Katalyse e.V. (LIKAT) an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Germany) http://www.catalysis.deSearch for more papers by this author Shoubhik Das, Shoubhik Das Leibniz-Institut für Katalyse e.V. (LIKAT) an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Germany) http://www.catalysis.deSearch for more papers by this authorDr. Daniele Addis, Dr. Daniele Addis Leibniz-Institut für Katalyse e.V. (LIKAT) an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Germany) http://www.catalysis.deSearch for more papers by this authorLeif R. Knöpke, Leif R. Knöpke Leibniz-Institut für Katalyse e.V. (LIKAT) an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Germany) http://www.catalysis.deSearch for more papers by this authorDr. Ursula Bentrup, Dr. Ursula Bentrup Leibniz-Institut für Katalyse e.V. (LIKAT) an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Germany) http://www.catalysis.deSearch for more papers by this authorDr. Kathrin Junge, Dr. Kathrin Junge Leibniz-Institut für Katalyse e.V. (LIKAT) an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Germany) http://www.catalysis.deSearch for more papers by this authorProf. Dr. Angelika Brückner, Prof. Dr. Angelika Brückner Leibniz-Institut für Katalyse e.V. (LIKAT) an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Germany) http://www.catalysis.deSearch for more papers by this authorProf. Dr. Matthias Beller, Corresponding Author Prof. Dr. Matthias Beller [email protected] Leibniz-Institut für Katalyse e.V. (LIKAT) an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Germany) http://www.catalysis.deLeibniz-Institut für Katalyse e.V. (LIKAT) an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock (Germany) http://www.catalysis.deSearch for more papers by this author First published: 24 August 2011 https://doi.org/10.1002/anie.201104226Citations: 110 † This work was funded by the State of Mecklenburg-Western Pomerania, the BMBF, and the DFG (Leibniz Prize). We thank Dr. W. Baumann, Dr. C. Fischer, S. Buchholz, S. Schareina, A. Kammer, A. Koch, B. Wendt, S. Rossmeisl, and K. Mevius (all at the LIKAT) for their excellent technical and analytical support. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Fluoride's new role: Selective and efficient monoreductions of imides can be achieved with polymethylhydrosiloxane (PMHS) and tetra-n-butylammonium fluoride (TBAF) as catalyst (see scheme). The system is characterized by good chemoselectivity, operational simplicity, and functional-group tolerance; a concise mechanistic proposal was possible from in situ spectroscopic investigations. Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_201104226_sm_miscellaneous_information.pdf3.9 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. 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